The coupling of arylboronic acids with electron-rich allylic bromides is accomplished in the absence of any transition-metal catalyst through conventional heating. The reaction is completely regioselective, affording only the α-coupled product, and can be carried out under mild aerobic conditions in an organic solvent; the presence of a base is required. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Autori: | |
Data di pubblicazione: | 2012 |
Titolo: | Catalyst-free Suzuki-type Coupling of Allylic Bromides with Arylboronic Acids |
Rivista: | EUROPEAN JOURNAL OF ORGANIC CHEMISTRY |
Digital Object Identifier (DOI): | http://dx.doi.org/10.1002/ejoc.201101527 |
Volume: | 2012 |
Appare nelle tipologie: | 2.1 Articolo su rivista |
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O201101527KAP1.pdf | Documento in Post-print | Accesso chiuso-personale | Open Access dal 15/10/2038 |
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