By passing a gaseous alkyl halide over a catalytic column composed of a salt, a solid support, and a phasetransfer catalyst, the substitution product is obtained. The phase-transfer catalyst can be either free or immobilized on a silica matrix; in this way syntheses of alkyl iodides and esters are possible. © 1979, American Chemical Society. All rights reserved.
Nucleophilic Substitution between a Gaseous Alkyl Halide and a Solid Salt, Promoted by Phase-Transfer Catalysts
TUNDO, Pietro
1979-01-01
Abstract
By passing a gaseous alkyl halide over a catalytic column composed of a salt, a solid support, and a phasetransfer catalyst, the substitution product is obtained. The phase-transfer catalyst can be either free or immobilized on a silica matrix; in this way syntheses of alkyl iodides and esters are possible. © 1979, American Chemical Society. All rights reserved.
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