Reversible encapsulation of [Ru(bpy)3]2+ within a self-assembled hexameric resorcin[4]arene capsule turns off the photocatalytic aerobic oxidation of an aliphatic sulfide. Upon addition of a competitive cationic guest, the Ru(II) catalyst is released into solution where its catalytic activity is restored
Reversible encapsulation of [Ru(bpy)3]2+ within a self-assembled hexameric resorcin[4]arene capsule turns off the photocatalytic aerobic oxidation of an aliphatic sulfide. Upon addition of a competitive cationic guest, the Ru(ii) catalyst is released into solution where its catalytic activity is restored. © 2012 Royal Society of Chemistry.
Autori: | |
Data di pubblicazione: | 2012 |
Titolo: | Switching the activity of a photoredox catalyst through reversible encapsulation and release |
Rivista: | CHEMICAL COMMUNICATIONS |
Digital Object Identifier (DOI): | http://dx.doi.org/10.1039/C2CC37374B |
Volume: | 48 |
Appare nelle tipologie: | 2.1 Articolo su rivista |
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