High catalytic activity of the PdCl2(PPh3)2–PPh3–AlCl3 system containing AlCl3 as promotor has been demonstrated in the reaction of hydroethoxycarbonylation of hexene-1 and octene-1 at low pressure of carbon(II) oxide (≤25 atm). The reaction yields linear and branched products. The optimal conditions of the process have been elaborated. The target products yield is 84.6–93.8%.

Hydroethoxycarbonylation of α-Olefins at Low Pressure of Carbon(II) Oxide in the Presence of the PdCl2(PPh3)2–PPh3–AlCl3 System

VAVASORI, Andrea
2017-01-01

Abstract

High catalytic activity of the PdCl2(PPh3)2–PPh3–AlCl3 system containing AlCl3 as promotor has been demonstrated in the reaction of hydroethoxycarbonylation of hexene-1 and octene-1 at low pressure of carbon(II) oxide (≤25 atm). The reaction yields linear and branched products. The optimal conditions of the process have been elaborated. The target products yield is 84.6–93.8%.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10278/3690363
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