The present review highlights relevant recent examples (2013-2018) of sustainable synthetic reactions involving phosphorus and sulfur ylides. These examples include catalytic, halide- and base-free Wittig olefination reactions and P-ylides as CO2 activators. They also include sustainable protocols for the synthesis of S-ylides and recent applications of these C1 synthons as carbene precursors and in selected rearrangement reactions.

Greener and Sustainable Applications of Phosphorous and Sulfur Ylides

Giulia Fiorani
Writing – Original Draft Preparation
;
Maurizio Selva
Writing – Review & Editing
;
Alvise Perosa
Writing – Review & Editing
2018-01-01

Abstract

The present review highlights relevant recent examples (2013-2018) of sustainable synthetic reactions involving phosphorus and sulfur ylides. These examples include catalytic, halide- and base-free Wittig olefination reactions and P-ylides as CO2 activators. They also include sustainable protocols for the synthesis of S-ylides and recent applications of these C1 synthons as carbene precursors and in selected rearrangement reactions.
2018
51
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10278/3709718
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