The Cu(I) coordination polymer [Cu3(μ3-I)3(μ-btzMe)(NCCH3)]n (btzMe = 1-methyl-1H-benzotriazole) was prepared and characterized by X-Ray diffraction. The compound showed strong green emission upon excitation with wavelengths below 475 nm, with lifetime of 47 μs. The emission was attributed to 3(X,M)LCT transition on the basis of experimental data and DFT calculations.

Luminescent copper(I) coordination polymer with 1-methyl-1H-benzotriazole, iodide and acetonitrile as ligands

Bortoluzzi M.;Enrichi F.;Vomiero A.
2019-01-01

Abstract

The Cu(I) coordination polymer [Cu3(μ3-I)3(μ-btzMe)(NCCH3)]n (btzMe = 1-methyl-1H-benzotriazole) was prepared and characterized by X-Ray diffraction. The compound showed strong green emission upon excitation with wavelengths below 475 nm, with lifetime of 47 μs. The emission was attributed to 3(X,M)LCT transition on the basis of experimental data and DFT calculations.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10278/3711555
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