An environmentally safe water-soluble new ligand (2-(1-(2-(methylthio)ethyl)-1H-1,2,3-triazol-4-yl)ethanol) (ligand 1) has been synthesized by the click reaction between (2-azidoethyl)(methyl)sulfane and 3-butyn-1-ol. The structure of the novel ligand was confirmed by NMR spectroscopy. In situ combination of ligand 1 with [Rh(COD)Cl]2 and [Rh (CO)2(acac)] (Rh: ligand = 1: 4) successfully employed for the biphasic catalytic hydroformylation of styrene. The formation of branched 2-phenylpropanol was confirmed by gas chromatogphic analysis. The recycled catalytic aqueous phase can be used three runs with remarkable catalytic efficiency.
|Data di pubblicazione:||2020|
|Titolo:||Synthesis of a water‑soluble thio‑triazole ligand for biphase rhodium catalyzed hydroformylation of styrene|
|Rivista:||SN APPLIED SCIENCES|
|Digital Object Identifier (DOI):||http://dx.doi.org/10.1007/s42452-020-03711-0|
|Appare nelle tipologie:||2.1 Articolo su rivista |
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