The water soluble pyridyl-triazole ligand sodium 2-(1-((pyridin-2-yl)methyl)-1H-1,2,3-triazol-4-yl)ethyl sulfate (Na1) has been successfully employed in combination with ruthenium and iridium for catalytic hydrogenation of C=C and C=O double bonds in water/toluene biphasic systems. Reaction of the ligand with [RuCl2(η6-p-cymene)]2 affords the new water soluble complex [RuCl(η6-p-cymene)(1)] (2) which has been found to be catalytically active in the water/organic solvent biphasic hydrogenation using styrene and 2-cyclohexen-1-one as model substrates. Very conveniently, the iridium based catalytic system is prepared by simply stirring in water [Ir(η4-COD)Cl]2 with Na1 (Ir:Na1 molar ratio = 1:4), the resulting solution is catalytically active and appears more efficient than 2. With both the Ru- and Ir-based systems the catalytically active aqueous phases can be used at least three times without loss of activity.
|Data di pubblicazione:||2015|
|Titolo:||A pyridyl-triazole ligand for ruthenium and iridium catalyzed C=C and C=O hydrogenations in water/organic solvent biphasic systems|
|Rivista:||APPLIED CATALYSIS A: GENERAL|
|Digital Object Identifier (DOI):||http://dx.doi.org/10.1016/j.apcata.2014.11.013|
|Appare nelle tipologie:||2.1 Articolo su rivista |