An iridium(III) hydride complex in solution catalyses the O 2-co-oxidation of cyclo-octene and H2 to cyclo-octanone and water, respectively, via a hydroperoxide intermediate.
Selective homogeneous catalytic oxidation of olefins using oxygen/hydrogen mixtures: Oxygen atom transfer from an iridium hydroperoxide
STRUKUL, Giorgio;
1982-01-01
Abstract
An iridium(III) hydride complex in solution catalyses the O 2-co-oxidation of cyclo-octene and H2 to cyclo-octanone and water, respectively, via a hydroperoxide intermediate.
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